The three-dimensional structure of 3,3',4,4'-tetrachlorobiphenyl, a dioxin-like polychlorinated biphenyl (PCB).

نویسندگان

  • Nadim S Shaikh
  • Sean Parkin
  • Gregor Luthe
  • Hans-Joachim Lehmler
چکیده

The crystal structure of PCB 77 (3,3',4,4'-tetrachlorobiphenyl, C(12)H(6)Cl(4)), a dioxin-like PCB congener, is described. The dihedral angle of PCB 77 is 43.94(6) degrees, which is slightly larger than calculated or experimental dihedral angles of biphenyl derivatives in solution but smaller than experimental dihedral angles in the gas phase.

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عنوان ژورنال:
  • Chemosphere

دوره 70 9  شماره 

صفحات  -

تاریخ انتشار 2008